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Chapter: 3 Chemistry
    Section: 3.1 The elements
        SubSection: 3.1.4 Composition of the Earth’s atmosphere

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3.1.4 Composition of the Earth′s atmosphere

The atmospheric composition data are abridged from US National Air and Space Administration (Washington, D.C.) model of the US standard atmosphere. This represents an idealised steady state from the surface up to 100 km relative to dry air at sea level.

(Parts in 106 of dry air by volume)

N2

O2

Ar

CO2

Ne

He

CH4

Kr

N2O

H2

O3

Xe

780 984

209 475

9340

314

18

5.2

2.0

1.14

0.5

0.5

0.4

0.086


The United Nations Environmental Programme (Data Report, 3rd edn, 1991–92) includes a collation for (at least) the period 1977–1989 of latitudinal differences in values of mean monthly concentrations of carbon dioxide, methane, nitrous oxide and fluorocarbons 11 and 12. Figure 1 (Parts 1, 2, 3 & 4) illustrates the 13-year rising trend in December levels of these four pollutants separately, for latitudes 71°N, 40°N, 19°N and 14°S and the South Pole.

Figure 2 portrays less clear cut trends, some first rising and then all falling, for sulphur dioxide mean concentrations in residential areas of 15 major cities of the world.

Figure 3 (Parts 1, 2, & 3) displays changes in anthropogenic emissions of carbon dioxide for 1970, 1980 and 1988, and of sulphur dioxide and oxides of nitrogen for 1980, 1984 and 1988, expressed in million tonnes per year and in proportion of the world total between continents. Data were abstracted and summarised by the UNEP from OECD reports and national statistics.


(Click the Images to view Larger Images)

CARBON DIOXIDE, as  parts/million by mole fraction (ppmf),measured by non-dispersive IR analyser

CARBON DIOXIDE, as parts/million by mole fraction (ppmf), measured by non-dispersive IR analyser
Fig. 1 (Part 1)



METHANE, as  parts/million by mole volume (ppmv),in dry air, measured by gc/fid
METHANE, as parts/million by volume (ppmv), in dry air, measured by gc/fid
Fig. 1 (Part 2)



NITROUS OXIDE, as  parts/million by mole fraction (ppmf),measured by gc/ecd

NITROUS OXIDE, as parts/million by mole fraction (ppmf), measured by gc/ecd
Fig. 1 (Part 3)



CFC11 (lower) & CFC12 (upper curve), as  parts/million by mole volume (ppmv), measured by gc/ecd
CFC11 (lower) & CFC12 (upper curve), as parts/million by volume (ppmv), measured by gc/ecd
Fig. 1 (Part 4)



SULPUR DIOXIDE, as micrograms per cubic metre

SULPUR DIOXIDE, as micrograms per cubic metre
Fig. 2



ANTHROPOGENIC EMISSIONS of Carbon Dioxide

Fig. 3 (Part 1)



ANTHROPOGENIC EMISSIONS of Sulphur Dioxide

Fig. 3 (Part 2)



ANTHROPOGENIC EMISSIONS of Nitrogen oxides

Fig. 3 (Part 3)


G.F.Phillips

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