 |
3.6.3 Densities ρ of aqueous solutions at the
thermodynamic temperature T; ρ° = kg.
m−3
The following table gives values of
ρ/ρ° for {xC2H5OH
+ (1 − x) H2O} at T = 293.15 K, x
denoting the mole fraction of C2H5OH.
|
x |
0.00 |
0.01 |
0.02 |
0.03 |
0.04 |
0.05 |
0.06 |
0.07 |
0.08 |
0.09 |
|
|
|
|
|
|
|
|
|
|
|
|
|
0.0 |
998.2 |
993.6 |
989.0 |
985.7 |
982.4 |
979.3 |
976.2 |
973.7 |
971.1 |
968.4 |
|
0.1 |
965.7 |
963.1 |
960.4 |
957.7 |
954.8 |
951.9 |
949.0 |
946.1 |
943.2 |
940.2 |
|
0.2 |
937.2 |
934.2 |
931.3 |
928.4 |
925.4 |
922.6 |
919.7 |
916.9 |
914.1 |
911.4 |
|
0.3 |
908.7 |
906.1 |
903.5 |
900.9 |
898.4 |
895.9 |
893.4 |
891.0 |
888.7 |
886.4 |
|
0.4 |
884.1 |
881.9 |
879.7 |
877.5 |
875.3 |
873.2 |
871.1 |
869.1 |
867.1 |
865.1 |
|
0.5 |
863.2 |
861.2 |
859.4 |
857.5 |
855.6 |
853.8 |
852.0 |
850.3 |
848.6 |
846.8 |
|
0.6 |
845.1 |
843.4 |
841.8 |
839.3 |
838.6 |
837.0 |
835.4 |
833.9 |
832.4 |
830.9 |
|
0.7 |
839.3 |
827.8 |
826.3 |
824.9 |
823.4 |
822.0 |
820.6 |
819.2 |
817.8 |
816.4 |
|
0.8 |
815.1 |
813.7 |
812.3 |
811.0 |
809.6 |
808.3 |
807.9 |
805.7 |
804.4 |
803.1 |
|
0.9 |
801.9 |
800.6 |
799.3 |
798.1 |
796.8 |
795.6 |
794.3 |
793.0 |
791.8 |
790.5 |
|
1.0 |
789.3 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
For other temperatures, interpolate from the above and the following
values of δ(ρ/ρ°) =
{ρ(T) − ρ(293.15
K)}/ρ°.
M.L.McGlashan
|
x |
0 |
0.1 |
0.2 |
0.3 |
0.4 |
0.5 |
0.6 |
0.7 |
0.8 |
0.9 |
1 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
At T = 298.15 K: |
1.1 |
2.4 |
3.6 |
4.0 |
4.2 |
4.3 |
4.4 |
4.4 |
4.4 |
4.3 |
4.2 |
|
At T = 288.15 K: |
−0.9 |
−2.3 |
−3.5 |
−4.0 |
−4.2 |
−4.3 |
−4.3 |
−4.3 |
−4.3 |
−4.3 |
−4.2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
Density ρ of {xHCl
+ (1 − x) H2O}, at T =
293.15 K, x denoting the mole fraction of HCl
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
1010 |
0.012 00 |
1050 |
0.055 18 |
1090 |
0.101 8 |
1130 |
0.151 9 |
1170 |
0.206 7 |
|
1020 |
0.022 44 |
1060 |
0.066 65 |
1100 |
0.113 9 |
1140 |
0.164 9 |
1180 |
0.221 8 |
|
1030 |
0.033 10 |
1070 |
0.078 06 |
1110 |
0.126 4 |
1150 |
0.178 5 |
1190 |
0.237 2 |
|
1040 |
0.044 05 |
1080 |
0.089 78 |
1120 |
0.139 0 |
1160 |
0.192 5 |
|
|
Density ρ of
{xHNO3 + (1 − x) H2O},
at T = 293.15 K, x denoting the mole fraction of
HNO3
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
1010 |
0.006 28 |
1120 |
0.069 84 |
1240 |
0.154 6 |
1360 |
0.289 3 |
1480 |
0.720 1 |
|
1020 |
0.011 72 |
1140 |
0.082 56 |
1260 |
0.172 3 |
1380 |
0.324 0 |
1490 |
0.801 8 |
|
1040 |
0.022 77 |
1160 |
0.095 63 |
1280 |
0.190 3 |
1400 |
0.366 2 |
1495 |
0.869 9 |
|
1060 |
0.034 06 |
1180 |
0.109 2 |
1300 |
0.211 3 |
1420 |
0.418 5 |
1500 |
0.925 8 |
|
1080 |
0.045 60 |
1200 |
0.123 3 |
1320 |
0.234 2 |
1440 |
0.484 3 |
1505 |
0.961 9 |
|
1100 |
0.057 81 |
1220 |
0.138 1 |
1340 |
0.260 0 |
1460 |
0.571 2 |
1510 |
0.986 1 |
Density ρ of
{xH2SO4 + (1 −
x) H2O}, at T = 293.15 K, x denoting the mole
fraction of H2SO4
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
1010 |
0.003 23 |
1260 |
0.090 0 |
1520 |
0.230 6 |
1780 |
0.513 2 |
1836.5 |
0.866 6 |
|
1020 |
0.006 12 |
1280 |
0.098 7 |
1540 |
0.244 6 |
1800 |
0.566 8 |
1836.0 |
0.902 8 |
|
1040 |
0.012 04 |
1300 |
0.107 8 |
1560 |
0.259 3 |
1810 |
0.603 5 |
1835.5 |
0.917 7 |
|
1060 |
0.018 12 |
1320 |
0.117 1 |
1580 |
0.274 8 |
1820 |
0.653 1 |
1835.0 |
0.930 7 |
|
1080 |
0.024 37 |
1340 |
0.126 9 |
1600 |
0.291 1 |
1822 |
0.665 3 |
1834.5 |
0.941 4 |
|
1100 |
0.030 75 |
1360 |
0.136 9 |
1620 |
0.308 3 |
1824 |
0.678 7 |
1834.0 |
0.949 9 |
|
1120 |
0.037 33 |
1380 |
0.146 7 |
1440 |
0.326 6 |
1826 |
0.694 1 |
1833.5 |
0.958 4 |
|
1140 |
0.044 11 |
1400 |
0.157 8 |
1660 |
0.345 9 |
1828 |
0.710 3 |
1833.0 |
0.965 6 |
|
1160 |
0.051 10 |
1420 |
0.168 9 |
1680 |
0.366 6 |
1830 |
0.730 0 |
1832.5 |
0.973 4 |
|
1180 |
0.058 33 |
1440 |
0.180 3 |
1700 |
0.389 3 |
1832 |
0.753 1 |
1832.0 |
0.980 2 |
|
1200 |
0.065 81 |
1460 |
0.192 1 |
1720 |
0.414 1 |
1834 |
0.783 5 |
1831.5 |
0.987 1 |
|
1220 |
0.073 56 |
1480 |
0.204 3 |
1740 |
0.441 7 |
1835 |
0.804 2 |
1831.0 |
0.993 5 |
|
1240 |
0.081 63 |
1500 |
0.217 1 |
1760 |
0.473 9 |
1836 |
0.837 6 |
1830.5 |
1.000 0 |
Density ρ of
{xNH3 + (1 − x)H2O}, at
T = 293.15 K, x denoting the mole fraction of
NH3
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
994 |
0.010 5 |
966 |
0.081 8 |
938 |
0.250 7 |
910 |
0.250 7 |
882 |
0.344 2 |
|
990 |
0.020 1 |
962 |
0.092 8 |
934 |
0.174 6 |
906 |
0.264 2 |
878 |
0.357 1 |
|
986 |
0.029 9 |
958 |
0.103 8 |
930 |
0.186 9 |
902 |
0.277 8 |
874 |
0.370 1 |
|
982 |
0.040 0 |
954 |
0.115 1 |
926 |
0.199 4 |
898 |
0.291 5 |
870 |
0.383 2 |
|
978 |
0.050 3 |
950 |
0.126 4 |
922 |
0.212 0 |
894 |
0.305 1 |
866 |
0.396 3 |
|
974 |
0.060 6 |
946 |
0.138 1 |
918 |
0.224 7 |
890 |
0.318 4 |
|
|
|
970 |
0.071 2 |
942 |
0.149 9 |
914 |
0.237 6 |
886 |
0.331 2 |
|
|
|
Density ρ of
{xNa2CO3 + (1 −
x)H2O}, at T = 293.15 K, x denoting the
mole fraction of Na2CO3 |
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
1010 |
0.001 95 |
1040 |
0.007 07 |
1070 |
0.012 43 |
1100 |
0.017 99 |
1130 |
0.023 73 |
|
1020 |
0.003 63 |
1050 |
0.008 83 |
1080 |
0.014 27 |
1110 |
0.019 88 |
1140 |
0.025 69 |
|
1030 |
0.005 33 |
1060 |
0.010 62 |
1090 |
0.016 11 |
1120 |
0.021 80 |
1145 |
0.026 66 |
|
Density ρ
of {xNaOH + (1 − x)H2O}, at
T = 293.15 K, x denoting the mole fraction of NaOH
|
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
1020 |
0.008 82 |
1130 |
0.057 45 |
1240 |
0.121 1 |
1350 |
0.175 6 |
1460 |
0.254 5 |
|
1030 |
0.012 99 |
1140 |
0.062 12 |
1250 |
0.117 5 |
1360 |
0.182 0 |
1470 |
0.262 6 |
|
1040 |
0.017 23 |
1150 |
0.066 89 |
1260 |
0.122 9 |
1370 |
0.188 6 |
1480 |
0.271 0 |
|
1050 |
0.021 52 |
1160 |
0.071 66 |
1270 |
0.128 4 |
1380 |
0.195 3 |
1490 |
0.279 6 |
|
1060 |
0.025 85 |
1170 |
0.076 53 |
1280 |
0.133 9 |
1390 |
0.202 1 |
1500 |
0.288 0 |
|
1070 |
0.030 23 |
1180 |
0.081 40 |
1290 |
0.139 6 |
1400 |
0.209 2 |
1510 |
0.296 8 |
|
1080 |
0.034 64 |
1190 |
0.086 38 |
1300 |
0.145 4 |
1410 |
0.216 3 |
1520 |
0.305 8 |
|
1090 |
0.039 08 |
1200 |
0.091 42 |
1310 |
0.151 2 |
1420 |
0.223 6 |
|
|
|
1100 |
0.043 60 |
1210 |
0.096 51 |
1320 |
0.157 1 |
1430 |
0.230 9 |
|
|
|
1110 |
0.048 17 |
1220 |
0.101 7 |
1330 |
0.163 1 |
1440 |
0.238 6 |
|
|
|
1120 |
0.052 78 |
1230 |
0.106 9 |
1340 |
0.169 3 |
1450 |
0.246 4 |
|
|
|
Density ρ
of {xH3PO4 + (1 −
x)H2O}, at T = 293.15 K, x denoting the
mole fraction of H3PO4 |
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
1010 |
0.004 02 |
1090 |
0.034 47 |
1240 |
0.101 9 |
1400 |
0.197 4 |
1720 |
0.567 7 |
|
1020 |
0.007 60 |
1100 |
0.038 46 |
1260 |
0.112 3 |
1440 |
0.226 5 |
1760 |
0.655 0 |
|
1030 |
0.011 27 |
1120 |
0.046 65 |
1280 |
0.123 2 |
1480 |
0.258 6 |
1780 |
0.704 2 |
|
1040 |
0.014 98 |
1140 |
0.055 07 |
1300 |
0.134 6 |
1520 |
0.294 4 |
1800 |
0.758 8 |
|
1050 |
0.018 78 |
1160 |
0.063 79 |
1320 |
0.146 1 |
1560 |
0.334 4 |
1820 |
0.818 4 |
|
1060 |
0.022 62 |
1180 |
0.072 81 |
1340 |
0.158 3 |
1600 |
0.380 2 |
1840 |
0.885 6 |
|
1070 |
0.026 53 |
1200 |
0.082 17 |
1360 |
0.170 8 |
1640 |
0.433 5 |
1860 |
0.959 5 |
|
1080 |
0.030 47 |
1220 |
0.091 99 |
1380 |
0.184 1 |
1680 |
0.494 9 |
|
|
|
Densities
ρ of {xB + (1 − x)H2O}, at the
thermodynamic temperature T, x denoting the mole fraction of
B |
|
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
ρ/ρ° |
x |
|
B = AgNO3, T = 293.15 K |
|
1042 |
0.005 55 |
1139 |
0.018 37 |
1255 |
0.034 14 |
1393 |
0.054 02 |
1565 |
0.079 84 |
|
1088 |
0.011 65 |
1194 |
0.025 83 |
1321 |
0.043 47 |
1474 |
0.066 03 |
1668 |
0.095 88 |
| |
|
B = BaCl2, T = 293.15 K |
|
1043 |
0.004 53 |
1092 |
0.009 52 |
1145 |
0.015 04 |
1203 |
0.021 17 |
1266 |
0.028 03 |
| |
|
B = CaCl2, T = 293.15 K |
|
1040 |
0.008 47 |
1129 |
0.027 85 |
1228 |
0.051 33 |
1337 |
0.080 38 |
|
|
|
1084 |
0.017 72 |
1178 |
0.039 00 |
1282 |
0.065 04 |
1396 |
0.097 65 |
|
|
| |
|
B = CdSO4, T = 293.15 K |
|
1049 |
0.004 53 |
1102 |
0.009 51 |
1161 |
0.015 02 |
1224 |
0.021 15 |
1295 |
0.028 00 |
| |
|
B = CuSO4, T = 293.15 K |
|
1051 |
0.005 91 |
1107 |
0.012 39 |
1167 |
0.019 53 |
1230 |
0.027 44 |
|
|
| |
|
B = FeCl3, T = 293.15 K
|
|
1041 |
0.005 81 |
1085 |
0.012 19 |
1132 |
0.019 22 |
1182 |
0.027 02 |
1234 |
0.035 70 |
| |
|
B = HClO4, T = 291.15 K
|
|
1029 |
0.009 35 |
1128 |
0.042 91 |
1251 |
0.088 06 |
1410 |
0.152 1 |
|
|
|
1060 |
0.019 54 |
1166 |
0.056 41 |
1299 |
0.106 8 |
1539 |
0.212 0 |
|
|
|
1093 |
0.030 68 |
1207 |
0.071 37 |
1352 |
0.128 0 |
1674 |
0.295 0 |
|
|
| |
|
B = H2O2, T = 288.15
K |
|
1017 |
0.027 12 |
1073 |
0.116 9 |
1133 |
0.221 9 |
1197 |
0.346 2 |
1341 |
0.679 3 |
|
1035 |
0.055 58 |
1092 |
0.150 1 |
1154 |
0.260 9 |
1242 |
0.442 7 |
1393 |
0.826 6 |
|
1054 |
0.085 48 |
1112 |
0.185 0 |
1175 |
0.302 3 |
1290 |
0.552 7 |
1447 |
1.000 0 |
| |
|
B = KBr, T = 293.15 K |
|
1035 |
0.007 90 |
1116 |
0.026 02 |
1208 |
0.048 04 |
1315 |
0.075 37 |
|
|
|
1074 |
0.016 54 |
1160 |
0.036 47 |
1259 |
0.060 93 |
1375 |
0.916 7 |
|
|
| |
|
B = K2CO3, T = 293.15
K |
|
1044 |
0.009 48 |
1139 |
0.031 08 |
1243 |
0.057 13 |
1355 |
0.089 15 |
1476 |
0.129 5 |
|
1090 |
0.019 80 |
1190 |
0.043 47 |
1298 |
0.072 27 |
1414 |
0.108 1 |
1540 |
0.153 8 |
| |
|
B = KCl, T = 293.15 K |
|
1030 |
0.012 56 |
1063 |
0.026 15 |
1098 |
0.040 90 |
1133 |
0.056 97 |
|
|
| |
|
B = K2Cr2O7,
T = 293.15 K |
|
1034 |
0.003 21 |
1070 |
0.006 76 |
|
|
|
|
|
|
| |
|
B = K3Fe(CN)6, T =
293.15 K |
|
1026 |
0.002 87 |
1054 |
0.006 04 |
1083 |
0.009 56 |
1113 |
0.013 49 |
|
|
| |
|
B = K4Fe(CN)6, T =
293.15 K |
|
1033 |
0.002 87 |
1068 |
0.006 04 |
1105 |
0.009 56 |
|
|
|
|
| |
|
B = KI, T = 293.15 K |
|
1036 |
0.005 68 |
1119 |
0.018 79 |
1216 |
0.034 91 |
1331 |
0.055 21 |
1467 |
0.081 55 |
|
1076 |
0.011 91 |
1166 |
0.026 41 |
1271 |
0.044 44 |
1396 |
0.067 47 |
1546 |
0.097 90 |
| |
|
B = KNO3, T = 293.15 K |
|
1030 |
0.009 29 |
1063 |
0.019 41 |
1097 |
0.030 49 |
1133 |
0.042 65 |
|
|
| |
|
B = K2SO4, T = 293.15
K |
|
1039 |
0.005 41 |
1082 |
0.011 36 |
|
|
|
|
|
|
| |
|
B = LiCl, T = 293.15 K |
|
1027 |
0.021 88 |
1085 |
0.069 76 |
1146 |
0.124 1 |
|
|
|
|
|
1056 |
0.045 09 |
1115 |
0.096 04 |
1179 |
0.154 1 |
|
|
|
|
| |
|
B = MgCl2, T = 293.15 K
|
|
1040 |
0.021 88 |
1082 |
0.045 09 |
1125 |
0.069 76 |
1171 |
0.096 04 |
1218 |
0.124 1 |
| |
|
B = MgSO4, T = 293.15 K
|
|
1050 |
0.007 82 |
1103 |
0.016 36 |
1160 |
0.025 73 |
1220 |
0.036 07 |
|
|
| |
|
B = NH4Cl, T = 293.15 K
|
|
1014 |
0.017 42 |
1029 |
0.036 07 |
1043 |
0.056 10 |
1057 |
0.077 66 |
|
|
| |
|
B = NH4NO3, T =
293.15 K |
|
1019 |
0.011 71 |
1061 |
0.038 20 |
1105 |
0.069 79 |
1151 |
0.108 1 |
1200 |
0.155 5 |
|
1040 |
0.024 40 |
1083 |
0.053 23 |
1128 |
0.087 97 |
1175 |
0.130 5 |
1226 |
0.183 7 |
| |
|
B = NaCl, T = 293.15 K |
|
1034 |
0.015 97 |
1071 |
0.033 12 |
1109 |
0.051 59 |
1148 |
0.071 55 |
1189 |
0.093 18 |
| |
|
B = NaNO3, T = 293.15 K
|
|
1032 |
0.011 03 |
1067 |
0.023 01 |
1104 |
0.036 06 |
1143 |
0.050 32 |
1183 |
0.065 99 |
| |
|
B = NaO2CCH3, T =
293.15 K |
|
1024 |
0.011 43 |
1050 |
0.023 82 |
1075 |
0.037 31 |
1102 |
0.052 04 |
1130 |
0.068 21 |
| |
|
B = Na2S2O3,
T = 293.15 K |
|
1040 |
0.005 96 |
1127 |
0.019 71 |
1223 |
0.036 59 |
1327 |
0.057 81 |
|
|
|
1083 |
0.012 50 |
1174 |
0.027 70 |
1274 |
0.046 56 |
1383 |
0.070 60 |
|
|
| |
|
B = Pb(O2CCH3)2,
T = 293.15 K |
|
1037 |
0.002 91 |
1120 |
0.009 68 |
1217 |
0.018 13 |
1330 |
0.028 96 |
|
|
|
1077 |
0.006 12 |
1166 |
0.013 66 |
1271 |
0.023 18 |
1399 |
0.035 61 |
|
|
| |
|
B = SrCl2, T = 293.15 K
|
|
1044 |
0.005 95 |
1093 |
0.012 47 |
1145 |
0.019 66 |
1201 |
0.027 63 |
1260 |
0.036 50 |
| |
|
B = ZnSO4, T = 293.15 K
|
|
1051 |
0.005 84 |
1107 |
0.012 25 |
1168 |
0.019 31 |
|
|
|
|
| |
|
B = C12H22O11
(sucrose), T = 293.15 K |
|
1018 |
0.005 84 |
1081 |
0.027 14 |
1151 |
0.056 68 |
1230 |
0.100 4 |
|
|
|
1038 |
0.012 25 |
1104 |
0.035 86 |
1176 |
0.069 24 |
1287 |
0.122 6 |
|
|
|
1059 |
0.019 31 |
1127 |
0.045 63 |
1203 |
0.083 66 |
1347 |
0.206 6 |
|
|
| |
|
|
|
|
|
|
|
|
|
M.L.McGlashan
|
 |