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Chapter: 3 Chemistry
    Section: 3.9 Electrochemistry
        SubSection: 3.9.9 Stability constants in aqueous solutions

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3.9.9 Stability constants in aqueous solutions

Extensive compilations of stability constant data Kn (or pKn = −log Kn) of step-wise, complex ion equilibria, involving ligand L and metal M, including (sometimes as well as) hydrogen, of the form

 

MLn−1  ←→  MLn

 
where  

Kn = [MLn/[MLn−1][L]

are available and it is not realistic to make a restricted selection here but instead to cite the compilations where values may be found.

References

E. Högfeldt (1982) Stability Constants, Part A Inorganic Ligands, Pergamon, Oxford.
A. E. Martell and R. M. Smith (1977) Critical Stability Constants, Plenum, New York.
D. D. Perrin (1979) Stability Constants, Part B Organic Ligands, Pergamon, Oxford.
L. D. Pettit and H. K. J. Powell (1993) IUPAC Stability Constants Database, Academic Software, Otley, W. Yorks LS21 2PW, UK. (This is a PC database which updates (1974–89) the earlier Chemical Society and IUPAC compilations and eventually will include entries from these.)
L. G. Sillen and A. E. Martell (1964) Stability Constants of Metal Ligand Complexes, Sp. Publ. 17, The Chemical Society, London.
L. G. Sillen and A. E. Martell (1968) Stability Constants Supplement 1, Spec. Publ. 25, The Chemical Society, London.

A.K. Covington

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