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2.7.9 Physical properties of sea water
The properties of sea water are a function of temperature, salinity
(i.e. total dissolved solids in g kg−1) and pressure. For the
sources of the data see M. Hill (ed.), The Sea, vol. 1, chap. 1 and vol.
4, pt. 1, chap. 18 (Wiley) and Cox et al., Deep Sea Res., 1970,
17, 679. For chemical composition
see
section 3.1.3.
Density ρ of sea water at
atmospheric pressure
|
|
Salinity/(g kg−1) |
|
20 |
25 |
30 |
35 |
40 |
|
(ρ/kg m−3 − 1000)* |
|
|
|
|
|
|
|
|
0 . . . . . . . . . |
16.04 |
20.06 |
24.08 |
28.10 |
32.14 |
|
5 . . . . . . . . . |
15.84 |
19.78 |
23.73 |
27.68 |
31.64 |
|
10 . . . . . . . . . |
15.31 |
19.18 |
23.07 |
26.96 |
30.86 |
|
15 . . . . . . . . . |
14.48 |
18.30 |
22.13 |
25.97 |
29.82 |
|
20 . . . . . . . . . |
13.39 |
17.17 |
20.96 |
24.75 |
28.56 |
|
25 . . . . . . . . . |
12.07 |
15.82 |
19.57 |
23.34 |
27.12 |
|
|
|
|
|
|
|
* In oceanographical work these
data are always expressed in terms of 1000(S − 1) where
S is the density relative to water at 4 °C. Values for this can be
obtained by adding 0.03 to the values in the table.
Density ρ of sea water at 0 °C
and salinity 35 g kg−1
|
Pressure/MPa |
0 |
20 |
40 |
60 |
80 |
100 |
|
(ρ/kg m−3 − 1000) |
28.10 |
37.44 |
46.37 |
54.92 |
63.12 |
71.02 |
Mechanical and thermal properties of sea water
at salinity 35 g kg−1 and atmospheric
pressure (unless otherwise stated)
|
|
|
|
|
|
Dynamic
viscosity . . . . . . . . . . |
|
1.88 × 10−3 Pa
s |
1.08 × 10−3 Pa
s |
|
Kinematic viscosity, ν
. . . . . . . . . |
|
1.83 × 10−6 m2
s−1 |
1.05 × 10−6 m2
s−1 |
|
Thermal conductivity
. . . . . . . . . |
|
0.563 W m−1
K−1 |
0.596 W m−1
K−1 |
|
Thermal diffusivity,
κ . . . . . . . . . |
|
1.37 × 10−7 m2
s−1 |
1.46 × 10−7
m2 s−1 |
|
Prandtl number, ν/κ
. . . . . . . . . |
|
13.4 |
7.2 |
|
Specific heat capacity,
Cp . . . . . . . . . .
|
|
3985 J kg−1
K−1 |
3993 J kg−1 K−1
|
|
Thermal expansion
coefficient . . . . . . . .
|
|
|
|
|
Pressure = 0.1 MN
m−2 . . . . . . . . .
|
|
52 × 10− 6 K−
1 |
250 × 10−6
K−1 |
|
Pressure = 100 MN
m−2 . . . . . . . . .
|
|
244 × 10− 6 K−
1 |
325 × 10−6
K−1 |
|
Ratio of specific heat capacities,
Cp /Cv
. . . |
|
1.000 4 |
1.010 6 |
|
Velocity of sound*
. . . . . . . . . . . . . .
|
|
1449 m s−1 |
1522 m s−1 |
|
Compressibility . . . . . . . . . . . . . . . .
|
|
4.65 × 10−10
Pa−1 |
4.28 × 10−10
Pa−1 |
|
Freezing
point . . . . . . . . . . . . . . . .
|
|
|
− 1.910 °C |
|
Boiling
point . . . . . . . . . . . . . . . .
|
|
|
100.56 °C |
|
*
See
also section 2.4.1. |
Electrical conductivity γ of sea
water at atmospheric pressure
|
|
|
Temperature |
|
Salinity / (g
kg−1) |
|
|
|
°C |
|
20 |
25 |
30 |
35 |
40 |
|
|
|
| |
γ / (S
m−1 ) |
|
0 . . . . . . . . . . . . . . . |
1.745 |
2.137 |
2.523 |
2.906 |
3.285 |
|
5 . . . . . . . . . . . . . . . |
2.015 |
2.466 |
2.909 |
3.346 |
3.778 |
|
10 . . . . . . . . . . . . . . . |
2.300 |
2.811 |
3.313 |
3.808 |
4.297 |
|
15 . . . . . . . . . . . . . . . |
2.595 |
3.170 |
3.735 |
4.290 |
4.837 |
|
20 . . . . . . . . . . . . . . . |
2.901 |
3.542 |
4.171 |
4.788 |
5.397 |
|
25 . . . . . . . . . . . . . . . |
3.217 |
3.926 |
4.621 |
5.302 |
5.974 |
|
|
|
|
|
|
|
At a depth of 4000 m the bottom water (about 0 °C,
salinity 35 g kg−1) has a conductivity 6% greater than the surface water.
The mean conductivity of the oceans (excluding the shallow seas) is 3.27
S m−1.
Sir Edward Bullard
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