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1.1 Units
1.1.1 The international system of units (SI)
History
In the second half of the nineteenth century the
centimetre, gram and second were in fairly general use as base units for
scientific work even in such countries as the UK and the USA where the foot and
the pound were employed for commerce and engineering. As a result, the units
required by the rapidly emerging science of electricity were based on the
centimetre, gram and second, with which they formed a coherent system known as
the CGS electromagnetic system. A system of units is said to be coherent when
derived units are formed from the base units without the insertion of factors
of proportionality other than unity. There was also the CGS electrostatic
system, but the only quantities frequently expressed in electrostatic units
were electric charge, electric potential, and capacitance.
The young but fast-growing electrical industry soon
found that many CGS electromagnetic units were of an extremely inconvenient
size for its needs. Accordingly, in 1881, international agreement was reached
to fix the practical unit of potential, to be called the volt, at
108 CGS units (which is approximately equal to the e.m.f. of a
primary cell), and the unit of resistance, the ohm, at 109 CGS units
(which is approximately the resistance of a column of mercury 1 m long and 1
mm2 in cross-section). The unit of electric current, the ampere, was
made a tenth of the CGS unit. A coherent system of practical electric units was
thus secured which, however, was not coherent with the mechanical units based
on the centimetre and gram. The practical electric units suited the needs of
telegraphy, which was then the main electrical industry, and they also happen
to be convenient for heavy electrical engineering and for electronics.
The magnetic units, however, were left at their CGS
values, presumably because the CGS unit of magnetic flux density, subsequently
called ‘gauss’, is of the order of the flux density of the
Earth’s field, and, as it was suitable for geomagnetism, there seemed no
point in changing it for a unit 104 times larger. Coherence was
thereby lost to electromagnetism as it had already been lost to the system
embracing the mechanical units and the practical electric units.
Whereas the electric units, by the agreement of 1881,
were chosen to be of suitable magnitude for everyday use, and whereas the
centimetre and the second have acceptable sizes, the gram is too small for the
practical needs of man, which are better served by a unit nearer the size of
the pound or the kilogram. Moreover, the CGS unit of force, the dyne, and the
unit of energy, the erg, are much too small. On the other hand, the unit of
energy provided by the practical electric units, the volt-ampere-second, called
the joule—which equals 107 ergs—is of a satisfactory
size.
These considerations—the advantages of coherence
and the fortuitous circumstance that a mechanical system based on the metre and
the kilogram has precisely the same unit of energy as is provided by the
practical electric units—led G. Giorgi in 1902 to propose a system based
on the metre, the kilogram, the second, and one of the
practical electric units. He pointed out that if magnetic field strength were
expressed as amperes per metre instead of 4π times amperes per metre, which is the
definition corresponding to that of the CGS unit, the number
π would disappear from most
electric and magnetic formulae involving rectilinear geometry, but would
appear, as is to be expected, in those involving cylinders or spheres.
The International Electrotechnical Commission eventually
chose the ampere as the fourth base unit of the MKSA or
‘Giorgi’ system, and in 1948 the 9th General Conference of Weights
and Measures† recommended it for science and technology, as
well as for commerce and industry. This system admirably covers mechanics and
electromagnetism, but it does not provide for other branches of science such as
heat. In 1960, in the hope of securing world-wide uniformity in the units
employed in natural science, the 11th CGPM added to the units metre, kilogram,
second and ampere, the kelvin for thermodynamic temperature, the
candela for luminous intensity, and the radian and steradian for plane
and solid angle. The first two joined the original four in being called
‘base’ units, and the last two were called
‘supplementary’ units. Any unit formed from two or more base units
is called ‘derived’. The radian and steradian are regarded as
derived units. The MKSA system thus broadened is called the International
System of Units, often abbreviated to SI, and is the most satisfactory system
of units we have had so far, in that it caters for the commercial and
industrial activities of man as well as for the needs of science. In 1971, the
14th CGPM added the mole, the unit of amount of substance used in
chemistry, to the list of base units, thus making them seven in all.
† The General Conference of
Weights and Measures (CGPM) is the authority set up by the Metre Convention of
1875 to promote and improve the metric system, and to secure international
uniformity in metric units and standards of measurement. It consists of
delegations from the member nations (of which there were 46, including the UK,
in 1982), which meet every few years, the 15th, 16th and 17th Conferences
having been held in 1975, 1979, and 1983. The International Bureau of Weights
and Measures (BIPM), Sèvres (near Paris) is the central office and
laboratory of the organization, and is managed, under the authority of the
General Conference, by the International Committee for Weights and Measures
(CIPM) consisting of 18 members, each from a different nation. The
International Committee meets yearly and is responsible for recommending
proposals for approval by the General Conference. Eight specialist advisory
committees assist the International Committee in planning co-operative
programmes of research, and in the preparation of recommendations on units of
measurement, on length (definition of the metre), mass, time (definition of the
second), temperature, electricity, photometry and radiometry, and ionizing
radiations.
Definitions of some SI units
The seven base quantities, each with its unit and unit symbol, are
listed below.
SI base quantities and units
|
Quantity |
Name of unit |
Unit symbol |
| |
|
|
|
Length . . . . . . . . . . . . . |
metre |
m |
|
Mass . . . . . . . . . . . . . . |
kilogram |
kg |
|
Time . . . . . . . . . . . . . . |
second |
s |
|
Electric current
. . . . . . . . . .
|
ampere |
A |
|
Thermodynamic
temperature . . . . .
|
kelvin
|
K |
|
Amount of
substance . . . . . . . . |
mole |
mol |
|
Luminous
intensity . . . . . . . . . |
candela |
cd |
|
|
|
|
The SI base units are defined as follows:
The metre is the length of the path
travelled by light in vacuum during a time interval of 1/299 792 458 of a
second. The kilogram is the unit of mass; it is equal to the mass
of the international prototype of the kilogram. The second is the
duration of 9 192 631 770 periods of the radiation corresponding to the
transition between the two hyperfine levels of the ground state of the
caesium-133 atom. The ampere is that constant current which, if
maintained in two straight parallel conductors of infinite length, of
negligible circular cross-section, and placed 1 metre apart in vacuum, would
produce between these conductors a force equal to 2 ×
10−7 newton per metre of length. The kelvin, unit
of thermodynamic temperature, is the fraction 1/273.16 of the thermodynamic
temperature of the triple point of water. The mole is the amount of
substance of a system which contains as many elementary entities as there are
atoms in 0.012 kilogram of carbon 12. When the mole is used, the elementary
entities must be specified and may be atoms, molecules, ions, electrons, other
particles, or specified groups of such particles. The candela is
the luminous intensity, in a given direction, of a source that emits
monochromatic radiation of frequency 540 × 1012 hertz and that
has a radiant intensity in that direction of (1/683) watt per steradian.
The SI supplementary units are defined thus:
The radian is the plane angle between two radii of a circle
which cut off on the circumference an arc equal in length to the radius.
The steradian is the solid angle which, having its vertex in the centre
of a sphere, cuts off an area of the surface of the sphere equal to that of a
square with sides of length equal to the radius of the sphere.
Derived units. The table below lists some of the more common SI
derived quantities, each with its unit and unit symbol. The composite symbols
in the last column are to some extent indicative of the definition of the
quantity.
|
Quantity |
Unit |
Symbol |
| |
|
|
|
|
Supplementary |
|
|
|
|
Plane
angle . . . . . . . . . . . .
|
radian |
rad |
|
|
Solid
angle . . . . . . . . . . . .
|
steradian |
sr |
|
| |
|
|
|
|
Derived |
|
|
|
|
Area . . . . . . . . . . . . .
|
square metre |
|
m2 |
|
Volume . . . . . . . . . . . . .
|
cubic metre |
|
m3 |
|
Frequency . . . . . . . . . . . .
|
hertz |
Hz |
s−1 |
|
Density . . . . . . . . . . . . .
|
kilogram per cubic metre |
|
kg m−3 |
|
Concentration . . . . . . . . . .
|
mole per cubic metre |
|
mol m−3 |
|
Velocity . . . . . . . . . . . .
|
metre per second |
|
m s−1 |
|
Angular
velocity . . . . . . . . . .
|
radian per second |
|
rad s−1 |
|
Acceleration . . . . . . . . . . .
|
metre per second squared |
|
m s−2 |
|
Angular
acceleration . . . . . . . .
|
radian per second squared |
|
rad s−2 |
|
Force . . . . . . . . . . . . .
|
newton |
N |
m kg s−2 |
|
Pressure,
stress . . . . . . . . . .
|
pascal |
Pa |
N m−2 |
|
Viscosity
(dynamic) . . . . . . . .
|
pascal second |
|
Pa s |
|
Viscosity
(kinematic) . . . . . . . .
|
metre squared per second |
|
m2 s−1 |
|
Energy, work, quantity of
heat . . . . .
|
joule |
J |
N m |
|
Power, radiant
flux . . . . . . . .
|
watt |
W |
J s−1 |
|
Quantity of electricity
|
coulomb |
C |
A s |
|
Potential difference,
electromotive
force
. . . . . . . .
. . . |
volt |
V |
W A−1 |
|
Electric field
strength . . . .
. . . |
volt per metre |
|
V m−1 |
|
Electric
resistance . . . .
. . . .
|
ohm |
Ω |
V A−1 |
|
Electric
conductance . . .
. . . .
|
siemens |
S |
W−1 |
|
Capacitance . . . . . . . .
. . . |
farad |
F |
CV−1 |
|
Magnetic
flux . . . . . . .
. . . |
weber |
Wb |
Vs |
|
Magnetic flux
density . . . .
. . . |
tesla |
T |
Wb m−2 |
|
Inductance . . . . . . .
. . . |
henry |
H |
W s |
|
Magnetic field
strength . . .
. . . |
ampere per metre |
|
A m−1 |
|
Magnetomotive
force . . .
. . . |
ampere |
A |
|
|
Wave
number* . . . . . .
. . . |
1 per radian |
|
m−1 |
|
Activity (of a
radionuclide) . .
. . . |
becquerel |
Bq |
s−1 |
|
Absorbed
dose . . . . . .
. . . |
gray |
Gy |
J kg−1 |
|
Dose
equivalent . . . . . .
. . . |
sievert |
Sv |
J kg−1 |
|
Luminous
flux . . . . . .
. . . |
lumen |
lm |
cd sr |
|
Luminance . . . . . .
. . . |
candela per square metre |
|
cd m−2 |
|
Illuminance . . . . . .
. . . |
lux |
lx |
lm m−2 |
|
Heat flux density,
irradiance . .
. . . |
watt per square metre |
|
W m−2 |
|
Heat capacity,
entropy .
. . . . .
|
joule per kelvin |
|
J K−1 |
|
Specific heat capacity,
specific |
|
|
|
|
entropy . . . . . .
. . . .
|
joule per kilogram kelvin |
|
J kg−1 K−1 |
|
Thermal
conductivity . . .
. . . .
|
watt per metre kelvin |
|
W m−1 K−1 |
|
Molar
energy . . . . . .
. . . .
|
joule per mole |
|
J mol−1 |
|
Molar entropy, molar
heat |
|
|
|
|
capacity .
. . . . .
. . . .
|
joule per mole kelvin |
|
J mol−1 K−1 |
|
|
|
|
|
*Wave numbers in the infra-red are still often expressed in
cm−1
Prefixes. Prefixes may be used, instead of powers of 10, to
express certain decimal multiples of the units. Their names and symbols are
listed below.
|
Factor |
Name |
Symbol |
Factor |
Name |
Symbol |
| |
|
|
|
|
|
|
1024 |
yotta |
Y |
10−1 |
deci |
d |
|
1021 |
zetta |
Z |
10−2 |
centi |
c |
|
1018 |
exa |
E |
10−3 |
milli |
m |
|
1015 |
peta |
P |
10−6 |
micro |
μ |
|
1012 |
tera |
T |
10−9 |
nano |
n |
|
109 |
giga |
G |
10−12 |
pico |
p |
|
106 |
mega |
M |
10−15 |
femto |
f |
|
103 |
kilo |
k |
10−18 |
atto |
a |
|
102 |
hecto |
h |
10−21 |
zepto |
z |
|
10 |
deca |
da |
10−24 |
yocto |
y |
|
|
|
|
|
|
|
An exponent attached to a symbol containing a prefix indicates that the
multiple of the unit is raised to the power expressed by the exponent.
Example: 1 cm3 = 10−6 m3; 1
cm−1 = 102 m−1.
Compound prefixes should not be used, e.g. use p not
μμ. Names of multiples
of the unit of mass are formed by attaching prefixes to the word
‘gram’.
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